Dalian Institute of Materials Research Development of Micro-Supercapacitors

Dalian Institute of Materials Research Development of Micro-Supercapacitors

Recently, Wu Zhongshuai, a researcher of the 2D Materials and Energy Devices Research Group of the Dalian Institute of Chemical Physics, Chinese Academy of Sciences, used a bottom-up pyrolysis method to prepare continuous, uniform, ultra-thin sulfur-doped graphene films, and applied them to them. High-capacity micro-supercapacitors, related research results published in the "American Chemical Society" (J. Am. Chem. Soc., DOI: 10.1021/jacs.7b00805). The work was focused on by Acta Physico-Chimica Sinica, a professor at Peking University, and Liu Zhongfan, an academician of the Chinese Academy of Sciences. He wrote on the bottom-up method of preparing sulfur-doped graphene films for miniaturization. The highlight of the article “Super Capacitors” (DOI: 10.3866/PKU.WHXB201703171) was followed by a Highlight report.

The rapid development of highly integrated, light-weight portable and functional structural integrated electronic devices urgently requires new energy storage devices that are compatible with them. Miniature supercapacitors have attracted much attention because of their advantages such as lightweight, small size, and high power density. Among them, the development of high-performance electrode materials is one of the important research directions for realizing high-performance miniature supercapacitors. The study found that one or more heteroatoms (nitrogen, boron, sulfur) doped graphene can significantly improve the performance of supercapacitors; however, with nanographene as the precursor, the uniform thickness from the bottom to the top is precisely prepared. The area of ​​sulfur-doped graphene films still faces great challenges.

The research team used the two-dimensional nano-confinement effect of nano-gold layer and gold catalysis to successfully prepare a continuous and uniform sulfur-doped graphene film from the bottom-up progressively pyrolysis method; this thin-film electrode was used. Micro-nano processing technology builds a miniature super capacitor. The capacitor has the advantages of high volumetric specific capacity (582F/cm3), good cycle stability, and high power density (1191 W/cm3). The mechanism study shows that the existence of nano-gold thin layer is conducive to the formation of stable S-Au bonds, CS bonds, thus achieving the complete structure of the nanographene main body, uniform doping of sulfur elements and uniform film thickness. This work provides a new idea for the controllable preparation of large-area, continuous graphene films from the bottom-up process; it also provides a new method for sulfur-doped graphene and confirms that sulfur doping can significantly improve the electrochemical performance of graphene films. performance.

The above work was funded by the National Natural Science Foundation of China, the National Key Research and Development Program, the Natural Science Foundation of Liaoning Province, and the National Youth 1000-member Program.

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